SYNTHESIS OF METHYL 4-O-[4-O-(ALPHA-D-GLUCOPYRANOSYL)-BETA-D-GLUCOPYRANOSYL]-BETA-D-MANNOPYRANOSIDE, A TRISACCHARIDE ANALOG RELATED TO THE REPEATING UNIT OF THE ANTIGEN FROM KLEBSIELLA TYPE-2

被引：0

作者：

MISRA, AK ^{[1
]}

ROY, N ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT BIOL CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1995年 / 34卷 / 10期

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D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl 3-O-allyl-2,6-di-O-benzyl-beta-D-mannopyranoside (7) has been synthesised from D-glucose. This synthon has been allowed to react with ethyl: 2,3,6,2:3',4',6'-hepta-O-acetyl-1-thio-beta-matopyranoside (9) using methyl triflate as promoter. Removal of protecting groups from the product affords methyl 4-O-[4-O-(alpha-D-glucopyranosyl)-beta-D-glucopyranosyl]-beta-D-mannopyranoside (12). The structure of 12 has been confirmed by its H-1 and C-13 NMR spectral data.

引用

页码：865 / 868

页数：4

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