STRUCTURE OF A 5-COORDINATED NICKEL-COMPLEX - [NI((C2H5O)2PS2)2P(C6H5)3]

被引：18
|
作者：
LIU, SX
LIN, CC
YU, YP
ZHU, DL
XU, Z
GOU, SH
YOU, XZ
机构：
[1] ZHENJIANG TEACHERS COLL,DEPT CHEM,JIANGSU,PEOPLES R CHINA
[2] NANJING UNIV,INST COORDINAT CHEM,NANJING,PEOPLES R CHINA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷
关键词：
D O I：
10.1107/S0108270190000968
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bis(O,O'-diethyl dithiophosphato)(triphenylphosphine)nickel(II), [Ni(C4H10O2PS2)2{P(C6H5)3}], M(r) = 691.45, triclinic, P1BAR, a = 12.985 (2), b = 13.748 (2), c = 9.389 (1) angstrom, alpha = 99.58 (1), beta = 99.10 (1), gamma = 84.12 (1)degrees, V = 1627.0 angstrom 3, Z = 2, D(x) = 1.41 g cm-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 10.18 cm-1, F(000) = 720, T = 295 K, final R = 0.062 for 5040 unique observations. The Ni atom in this molecule is coordinated by four S atoms and one P atom, forming a square pyramid. The triphenylphosphine moiety is planar.
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页码：43 / 45
页数：3
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