TRIGONAL-BIPYRAMIDAL AND SQUARE-PYRAMIDAL TUNGSTACYCLOBUTANE INTERMEDIATES ARE BOTH PRESENT IN SYSTEMS IN WHICH OLEFINS ARE METATHESIZED BY COMPLEXES OF THE TYPE W(CHR')(N-2,6-C6H3-I-PR2)(OR)2

被引：60

作者：

FELDMAN, J ^{[1
]}

DAVIS, WM ^{[1
]}

SCHROCK, RR ^{[1
]}

机构：

[1] MIT,DEPT CHEM,ROOM 6-331,CAMBRIDGE,MA 02139

来源：

ORGANOMETALLICS | 1989年 / 8卷 / 09期

关键词：

D O I：

10.1021/om00111a026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2266 / 2268

页数：3

共 18 条

[1] PREPARATION AND REACTIVITY OF SEVERAL ALKYLIDENE COMPLEXES OF THE TYPE W(CHR')(N-2,6-C6H3-I-PR2)(OR)2 AND RELATED TUNGSTACYCLOBUTANE COMPLEXES - CONTROLLING METATHESIS ACTIVITY THROUGH THE CHOICE OF ALKOXIDE LIGAND
SCHROCK, RR
DEPUE, RT
FELDMAN, J
SCHAVERIEN, CJ
DEWAN, JC
LIU, AH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) : 1423 - 1435
[2] SYNTHESIS AND REACTIVITY OF [RE(N-2,6-C6H3-I-PR2)3]- AND THE X-RAY STRUCTURE OF HG[RE(N-2,6-C6H3-I-PR2)3]2
WILLIAMS, DS
ANHAUS, JT
SCHOFIELD, MH
SCHROCK, RR
DAVIS, WM
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) : 5480 - 5481
[3] Reactions of M(N-2,6-i-Pr2C6H3)(CHR)(CH2R′)2 (M = Mo, W) complexes with alcohols to give olefin metathesis catalysts of the type M(N-2,6-i-Pr2C6H3)(CHR)(CH2R′)(OR")
Sinha, A
Lopez, LPH
Schrock, RR
Hock, AS
Müller, P
ORGANOMETALLICS, 2006, 25 (06) : 1412 - 1423
[4] THE PREPARATION AND REACTIVITY OF SEVERAL ALKYLIDENE COMPLEXES OF THE TYPE W(CHR')(N-2,6-C6H3-IPR2)(OR)2 AND RELATED TUNGSTACYCLOBUTANE COMPLEXES - HOW THE CHOICE OF OR LIGAND CONTROLS STRUCTURE AND METATHESIS ACTIVITY
FELDMAN, J
DEPUE, RT
SCHAVERIEN, CJ
DAVIS, WM
SCHROCK, RR
ADVANCES IN METAL CARBENE CHEMISTRY, 1989, 269 : 323 - 346
[5] REACTION OF NEOPENTYLIDENE COMPLEXES OF THE TYPE M(CH-T-BU)(N-2,6-C6H3-I-PR2)(OR)2 (M = W, MO) WITH METHYL ACRYLATE AND N,N-DIMETHYLACRYLAMIDE TO GIVE METALLACYCLOBUTANE COMPLEXES
FELDMAN, J
MURDZEK, JS
DAVIS, WM
SCHROCK, RR
ORGANOMETALLICS, 1989, 8 (09) : 2260 - 2265
[6] THIOLATO DINITROGEN (OR HYDRAZIDO(4-)) COMPLEXES, [TA(SAR)3(THF)]2(MU-N2) (AR = 2,6-C6H3-I-PR2, 2,4,6-C6H2-I-PR3), AND PHENOXIDE ANALOGS - STRUCTURAL COMPARISON OF [TA(S-2,6-C6H3-I-PR2)3(THF)]2(MU-N2) AND [TA(O-2,6-C6H3-I-PR2)3(THF)]2(MU-N2)
SCHROCK, RR
WESOLEK, M
LIU, AH
WALLACE, KC
DEWAN, JC
INORGANIC CHEMISTRY, 1988, 27 (12) : 2050 - 2054
[7] Living ring-opening metathesis polymerization of 2,3-difunctionalized 7-oxanorbornenes and 7-oxanorbornadienes by Mo(CHCMe2R)(N-2,6-C6H3-i-Pr2)(O-t-Bu)2 and Mo(CHCMe2R)(N-2,6-C6H3-i-Pr2)(OCMe2CF3)$ -2$/
1600, (113):
[8] HIGH OXIDATION-STATE COMPOUNDS CONTAINING HYDRAZINE AND HYDRAZIDO LIGANDS BOUND TO A W(N-2,6-C6H3-I-PR2)[2,6-NC5H3(CH2NTOSYL)2] CORE
CAI, S
SCHROCK, RR
INORGANIC CHEMISTRY, 1991, 30 (22) : 4105 - 4106
[9] ARYLOXIDE LIGANDS IN THE METATHESIS OF OLEFINS - SYNTHESES OF W(OAR)XCL6-X COMPLEXES WITH X = 2, 3, AND 4 - CRYSTAL-STRUCTURES OF W(O-2,6-C6H3-I-PR2)3CL3 AND W(O-2,6-C6H3PH2)2CL4
QUIGNARD, F
LECONTE, M
BASSET, JM
HSU, LY
ALEXANDER, JJ
SHORE, SG
INORGANIC CHEMISTRY, 1987, 26 (25) : 4272 - 4277
[10] Living ring-opening metathesis polymerization of 2,3-difunctionalized norbornadienes by Mo(CH-t-Bu)(N-2,6-C6H3-i-Pr2)(O-t-Bu)2
1600, (112):

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