High Performance Photorefractive Materials Based on Nematic-Like Mesophase Photoconductive Polymer

被引:0
|
作者
Kwon, O-Pil [1 ]
Kwon, Seong-Ji [1 ,2 ]
Jazbinsek, Mojca [1 ]
Guenter, Peter [1 ]
Lee, Suck-Hyun [2 ]
机构
[1] Swiss Fed Inst Technol, ETH Honggerberg, Inst Quantum Elect, Nonlinear Opt Lab, CH-8093 Zurich, Switzerland
[2] Ajou Univ, Dept Mol Sci & Technol, Suwon 442749, South Korea
关键词
photoconductive materials; photorefractive materials; photorefractive nonlinear optics; layered structure; mesophase structure; guest-host system;
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A new nematic-like mesophase photoconductive polymer PPT-TPA consisting of wholly aromatic rigid backbone of poly(p-phenyleneterephthalate),PPT and pendent hole-transporting (TPA) groups attached to the ends of oxyalkyl spacers has been synthesized. The correlation between the mesophase structure and the optical/physical properties of the photorefractive composite is investigated by X-ray diffraction, and photorefractive experiments. Despite a lower photoconductivity of the new photorefractive PPT-TPA composite, this material shows a higher photorefractive previously sensitivity S-n2 = 2 +/- cm 0.2cm(2)/kJ at E = 50 V/mu m than the previously synthesized PPT-CZ composite with a different photoconducting groups that exhibits a highly-ordered layered structure.
引用
收藏
页码:155 / 158
页数:4
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