Conductance behaviour of silver [cryptand 2,2,2] perchlorate complex in water-acetonitrile and methanol acetonitrile mixtures

被引：3
|
作者：
Raghunath, R
Kalidas, C
机构：
[1] Department of Chemistry, Indian Institute of Technology
来源：
PHYSICS AND CHEMISTRY OF LIQUIDS | 1995年 / 29卷 / 04期
关键词：
conductance of silver [cryptand 2,2,2] perchlorate complex; water-acetonitrile mixtures; methanol-acetonitrile mixtures;
D O I：
10.1080/00319109508031641
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Conductance studies on silver [Cryptand 2,2,2] perchlorate complex have been made in water-acetonitrile and methanol-acetonitrile mixtures over the complete range of solvent compositions at 30 degrees C. The data were analysed by the Fuoss 1980 three parameter equation and the variation of the Walden products of respective ions with solvent composition was analysed. The considerable decrease of the Walden products of {silver [Cryptand 2,2,2]}(+) has been explained in terms of the selective solvation of the ion by acetonitrile in both solvent mixtures.
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页码：237 / 241
页数：5
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