SYNTHESIS AND CHARACTERIZATION OF HIGHLY CONDUCTING POLYACETYLENE

被引：31
|
作者：
SHIRAKAWA, H
机构：
[1] Institute of Materials Science, University of Tsukuba, Tsukuba, Ibaraki
来源：
SYNTHETIC METALS | 1995年 / 69卷 / 1-3期
关键词：
D O I：
10.1016/0379-6779(94)02340-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Polyacetylene can be Synthesized by several routes. Among them, the most widely used method is an interfacial polymerization of acetylene monomer on a surface of a concentrated homogeneous Ziegler-Natta catalyst solution. The product is obtained as a form of thin films, which are served as specimens for characterization and measurements of various properties. The quality of the films is dependent strongly on preparative method of the catalyst as well as the polymerization condition of acetylene because there is no way to process the film due to its insolubility and infusibility. Synthetic conditions of highly characterization are reviewed in terms of catalyst preparations and polymerization methods.
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页码：3 / 8
页数：6
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