DETERMINATION OF KINETIC-PARAMETERS OF INORGANIC METALPORPHYRINS

被引：1
|
作者：
QU, LY
MA, RH
CHEN, YG
CHEN, Y
LIU, CT
机构：
[1] NE NORMAL UNIV,CTR ANAL & MEASUREMENT,CHANGCHUN 130024,PEOPLES R CHINA
[2] QIQIHAER CENT STN MONITORING ENVIRONM,QIQIHAER 161006,PEOPLES R CHINA
来源：
JOURNAL OF THERMAL ANALYSIS | 1995年 / 45卷 / 1-2期
关键词：
ACTIVATION ENERGY; HETEROPOLY TUNGSTOSILICATE; REACTION ORDER; THERMAL ANALYSIS; THERMAL PROPERTY;
D O I：
10.1007/BF02548691
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The thermal properties of four heteropoly complexes alpha-K3H3[SiW11Ni(H2O)O-39]. 11.5H(2)O (I), alpha-K3H2[SiW11Fe(H2O)O-39]. 9H(2)O (II), alpha-[(C4H9)(4)N]H-3.5(1.5)[SiW11Fe(H2O)O-39]. 4.5H(2)O (III) and alpha-[(C4H9)(4)N]H-3.5(2.5)[SiW11Cu(H2O)O-39]. 6H(2)O (IV) were studied by means of TG, DTA and DSC. The activation energy and reaction order of the thermal decomposition reaction of these complexes have been calculated.
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页码：275 / 287
页数：13
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