RAMAN-SPECTROSCOPIC AND DIFFERENTIAL SCANNING CALORIMETRIC STUDIES OF THE LIGHT-INDUCED METASTABLE STATES IN K2[RUCL5NO]

被引：78

作者：

WOIKE, T ^{[1
]}

ZOLLNER, H ^{[1
]}

KRASSER, W ^{[1
]}

HAUSSUHL, S ^{[1
]}

机构：

[1] UNIV COLOGNE, INST KRISTALLOG, W-5000 COLOGNE 1, GERMANY

来源：

SOLID STATE COMMUNICATIONS | 1990年 / 73卷 / 02期

关键词：

D O I：

10.1016/0038-1098(90)91036-G

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

In K2[RuCl5NO] light-induced long-living metastable states can be generated similar to those in Na2[Fe(CN)5NO] · 2H2O and other nitrosylprussides revealing the decisive role of the NO ligand for the formation of the new states. With Raman spectroscopy intramolecular and lattice vibrations were investigated during the population process and in the state of saturation. Only the frequencies of the internal modes are shifted. The thermally induced decay was investigated by differential scanning calorimetry, yielding information about the decay temperature, the activation energy, the frequency factor and the order of reaction. © 1990.

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页码：149 / 152

页数：4

共 18 条

[1] Raman-spectroscopic and differential scanning calorimetric studies of the light induced metastable states in K2[RuCl5NO]
Woike, Th., 1600, (73):
[2] INFRARED-SPECTROSCOPIC AND DIFFERENTIAL SCANNING CALORIMETRIC STUDIES OF THE 2 LIGHT-INDUCED METASTABLE STATES IN K2[RU(NO2)4(OH)(NO)]
WOIKE, T
HAUSSUHL, S
SOLID STATE COMMUNICATIONS, 1993, 86 (05) : 333 - 337
[3] POLARIZED RAMAN AND IR-SPECTRA OF K2[RUCL5NO]
TOSI, L
JOURNAL OF RAMAN SPECTROSCOPY, 1977, 6 (01) : 20 - 25
[4] DIFFERENTIAL SCANNING CALORIMETRIC AND RAMAN-SPECTROSCOPIC STUDY OF POLYMORPHISM IN NA2SO4
CODY, CA
DICARLO, L
DARLINGTON, RK
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (02): : 398 - 400
[5] Infrared spectra of K2[RuCl5NO] in two excited metastable states and the evidence for the NO linkage photoisomerization of metastable state I (MSI) in [RuX5NO]2- (X = Cl, CN)
Güida, JA
Ramos, MA
Piro, OE
Aymonino, PJ
JOURNAL OF MOLECULAR STRUCTURE, 2002, 609 (1-3) : 39 - 46
[6] RAMAN-SPECTROSCOPIC AND DIFFERENTIAL SCANNING CALORIMETRIC STUDIES OF THE EFFECT OF ETHANOL ON THE THERMODYNAMIC AND STRUCTURAL-PROPERTIES OF DIPALMITOYLPHOSPHATIDYLCHOLINE BILAYERS
DEVLIN, MT
LEVIN, IW
BIOPHYSICAL JOURNAL, 1990, 57 (02) : A272 - A272
[7] RAMAN-SPECTROSCOPIC AND OPTICAL STUDY ON THE LIGHT-INDUCED METASTABLE STATE OF NA2[FE(CN)5NO].2H2O SINGLE-CRYSTAL
MORIOKA, Y
HAMAGUCHI, H
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1992, 53 (07) : 967 - 971
[8] Evidence for two light-induced metastable states in Cl3[Ru(NH3)5NO]H2O
Schaniel, D
Woike, T
Boskovic, C
Güdel, HU
CHEMICAL PHYSICS LETTERS, 2004, 390 (4-6) : 347 - 351
[9] POPULATION-DYNAMICS OF THE 2 LIGHT-INDUCED METASTABLE STATES IN NA2[FE(CN)5NO].2H2O SINGLE-CRYSTALS
WOIKE, T
KRASSER, W
ZOLLNER, H
KIRCHNER, W
HAUSSUHL, S
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1993, 25 (04): : 351 - 356
[10] THE EXISTENCE OF LIGHT-INDUCED LONG-LIVED METASTABLE STATES IN DIFFERENT XN[FE(CN)5NO].YH2O CRYSTALS, POWDERS AND SOLUTIONS
ZOLLNER, H
KRASSER, W
WOIKE, T
HAUSSUHL, S
CHEMICAL PHYSICS LETTERS, 1989, 161 (06) : 497 - 501

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