ENZYMATIC RESOLUTION OF PLANAR CHIRAL FERROCENE DERIVATIVES

被引：0
|
作者：
IZUMI, T
HINO, T
机构：
来源：
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 1992年 / 55卷 / 04期
关键词：
BAKERS YEAST; LIPOZYME; LIPASE-P; FERROCENES; ENANTIOSELECTIVE REDUCTION; TRANSESTERIFICATION;
D O I：
暂无
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
Racemic 3-methyl, 2-ethyl, 2-bromo, and 2-trimethylsilyl derivatives of formylferrocene were kinetically resolved by enantioselective reduction with a fermenting baker's yeast. Moreover, 2-methyl, 3-methyl, 2-ethyl, 2-bromo, and 2-trimethylsilyl derivatives of hydroxymethylferrocene were optically resolved with lipases by transesterification using vinyl esters.
引用
收藏
页码：325 / 331
页数：7
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