ION-PAIR FORMATION IN SOLUTIONS OF LITHIUM-ACETATE IN ACETONITRILE WATER MIXTURES AT 25-DEGREES-C - A CONDUCTOMETRIC STUDY

被引：0

作者：

RAJU, K ^{[1
]}

MANAIAH, V ^{[1
]}

SETHURAM, B ^{[1
]}

RAO, TN ^{[1
]}

机构：

[1] OSMANIA UNIV,DEPT CHEM,HYDERABAD 500007,ANDHRA PRADESH,INDIA

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 1990年 / 22卷 / 03期

关键词：

CONDUCTANCE; LITHIUM ACETATE; ACETONITRILE-WATER; ASSOCIATION CONSTANTS; ION-PAIRS;

D O I：

10.1080/00319109008028806

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conductance of lithium acetate in 0-90% acetonitrile-water mixtures at 25°C were measured. The association constants were calculated using the Fuoss-Hsia equation with Fernandez-Prini coefficients. The logkavs. 1/D plot was a straight line in accordance with the modified Denison-Ramsey theory of ion-pair formation. Walden products were also calculated. The results are interpreted in terms of solvent separated ion-pairs and contact ion-pairs. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：163 / 167

页数：5

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