Organic conductor θ-(BEDT-TTF)Cd1.38I3 with layered perovskite-like structure

被引：0
|
作者：
E. I. Zhilyaeva
G. V. Shilov
A. M. Flakina
R. N. Lyubovskaya
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2018年 / 67卷
关键词：
radical cation salts; iodocadmates(II); crystal structure; electrical conductivity; layered perovskite-like structure;
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摘要：
The organic conductor θ-(BEDT-TTF)Cd1.38I3 (1) (BEDT-TTF is bis(ethylenedithio)- tetrathiafulvalene) with layered perovskite-like structure was synthesized. In the crystal structure of 1, θ-type organic conducting layers, which are built up from BEDT-TTF stacks, alternate with inorganic insulating layers. The latter are composed of CdI6 octahedra and CdI4 tetrahedra linked together to form a two-dimensional anionic network. Measurements of the temperature dependence of the electrical resistance demonstrated that compound 1 is a semiconductor.
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页码：252 / 254
页数：2
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