Enthalpies of the formation of aliphatic carbonyl-containing radicals

被引：0
|
作者：
Yu. D. Orlov
E. M. Chernova
V. V. Turovtsev
机构：
[1] Tver State University,
来源：
Russian Journal of Physical Chemistry A | 2012年 / 86卷
关键词：
free radicals; enthalpy of the formation; “structure-property” relation; additive group approach;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A collection of data on enthalpies of the formation(ΔfHo) of aliphatic carbonyl-containing radicals is analyzed and expanded. The ΔfHo values for 29 carbonyl-containing radicals are determined for the first time, and are strongly revised for 17 carbonyl-containing radicals using the literature data on the dissociation energies of the bonds in molecules. The data is analyzed on the basis of the structureproperty (enthalpy of formation) relation within the additive-group approach, with the determination and specification of the parameters. It is concluded that the ΔfHo values of carbonyl-containing radicals calculated from the obtained parameters (a total of 96 compounds was considered) agree well with the experimental data.
引用
收藏
页码：175 / 183
页数：8
相关论文
共 50 条
  • [1] Enthalpies of the formation of aliphatic carbonyl-containing radicals
    Orlov, Yu. D.
    Chernova, E. M.
    Turovtsev, V. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (02) : 175 - 183
  • [2] Branching Ratios for the Reaction of Selected Carbonyl-Containing Peroxy Radicals with Hydroperoxy Radicals
    Hasson, Alam S.
    Tyndall, Geoffrey S.
    Orlando, John J.
    Singh, Sukhdeep
    Hernandez, Samuel Q.
    Campbell, Sean
    Ibarra, Yesenia
    JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (24): : 6264 - 6281
  • [3] ON THE POSSIBLE FORMATION OF METALLOCHELATES ON THE BASIS OF CARBONYL-CONTAINING OLIGOMERS
    Voronchikhin, V. D.
    IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA, 2018, 8 (02): : 145 - 147
  • [4] Formylation of carbonyl-containing spirohydrochromans
    Fedotova O.V.
    Lipatova E.V.
    Tsimbalenko D.A.
    Shcherbakov A.A.
    Chemistry of Heterocyclic Compounds, 1998, 34 (3) : 378 - 379
  • [5] CARBONYL-CONTAINING ORGANOGERMANIUM COMPOUNDS
    MIRONOV, VF
    TSOTADZE, MV
    GAR, TK
    GVERDTSITELI, IM
    ZHURNAL OBSHCHEI KHIMII, 1975, 45 (10): : 2185 - 2189
  • [6] Fungicidal carbonyl-containing heterocycles
    Stevenson, Thomas M.
    Tiscione, Teodorica C.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [7] Formylation of carbonyl-containing spirohydrochromans
    Fedotova, OV
    Lipatova, EV
    Tsimbalenko, DA
    Shcherbakov, AA
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1998, (03): : 413 - 414
  • [8] Hydrogen peroxide formation in the oxidation of carbonyl-containing compounds at β-CH bonds
    Yu. V. Nepomnyashchikh
    I. M. Nosacheva
    A. L. Perkel’
    Kinetics and Catalysis, 2004, 45 (6) : 768 - 773
  • [9] Hydrogen peroxide formation in the oxidation of carbonyl-containing compounds at β-CH bonds
    Yu. V. Nepomnyashchikh
    I. M. Nosacheva
    A. L. Perkel’
    Kinetics and Catalysis, 2004, 45 : 768 - 773
  • [10] Hydrogen peroxide formation in the oxidation of carbonyl-containing compounds at β-CH bonds
    Nepomnyashchikh, YV
    Nosacheva, IM
    Perkel', AL
    KINETICS AND CATALYSIS, 2004, 45 (06) : 768 - 773
12345