The use of a new ionic phosphite ligand in the hydroformylation catalyzed by rhodium complexes: Effect of reaction media

被引：0
|
作者：
S. E. Lyubimov
E. A. Rastorguev
V. A. Davankov
机构：
[1] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Journal of Physical Chemistry B | 2014年 / 8卷
关键词：
ionic phosphite; hydroformylation; supercritical carbon dioxide; ionic liquids; rhodium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new method for the preparation of ionic phosphite ligands is developed. A first example of the use of this type of ligands in the hydroformylation catalyzed by rhodium complexes and conducted in organic solvents, an ionic liquid (IL), and supercritical carbon dioxide (SC-CO2) is described. It is shown that conducting the reaction in ionic liquid/supercritical carbon dioxide biphasic system may aid in increasing its rate.
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页码：953 / 957
页数：4
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