Synthesis of β-Fluoroalkyl-β,β-dimethoxy Ketones and β-Fluoroalkyl-β-methoxy-α,β-enones

被引：0

作者：

A. M. Pavlov

D. L. Chizhov

V. N. Charushin

机构：

[1] Russian Academy of Sciences,Postovskii Institute of Organic Synthesis, Ural Division

来源：

Russian Journal of Organic Chemistry | 2005年 / 41卷

关键词：

Sodium; Methanol; Organic Chemistry; Ketone; Methoxide;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

α-Bromo-β-fluoroalkyl-α,β-enones react with sodium methoxide in methanol to give the corresponding β-fluoroalkyl-β,β-dimethoxy ketones which eliminate methanol molecule to produce a mixture of E/Z-isomeric β-fluoroalkyl-β-methoxyvinyl ketones, the Z isomer prevailing.

引用

页码：1449 / 1451

页数：2

共 32 条

[1] Synthesis of β-fluoroalkyl-β,β-dimethoxy ketones and β-fluoroalkyl-β-methoxy-α,β-enones
Pavlov, AM
Chizhov, DL
Charushin, VN
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 41 (10) : 1449 - 1451
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[9] Polymers of fluoroalkyl- and semifluoroalkyl-substituted thiophenes.
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[10] Lewis Acid-Catalyzed Rearrangement of Fluoroalkylated Propargylic Alcohols: An Alternative Approach to β-Fluoroalkyl-α,β-enones
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