Electrochemical Behavior and Passive Film Composition of a High-Nitrogen Nickel-Free Austenitic Stainless Steel

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作者
Yanxin Qiao
Xinyi Wang
Jian Chen
Lanlan Yang
Xiaojing Wang
Huiling Zhou
Jiasheng Zou
机构
[1] Jiangsu University of Science and Technology,School of Materials Science and Engineering
[2] Western University,Department of Chemistry
关键词
High-nitrogen stainless steel; Corrosion; Electrochemical; Passive film; XPS;
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摘要
The electrochemical corrosion behavior of an aged Fe-18Cr-15Mn-0.66 N high-nitrogen austenitic stainless steel in 3.5 wt.% NaCl solution was studied using the measurements of polarization curves and electrochemical impedance spectroscopy, and the composition of the passive films formed on the HNSS was investigated using x-ray photoelectron spectroscopy (XPS). XPS analyses results showed that the passive films formed in this solution were composed of Cr oxide/hydroxide (mainly) and iron oxides (partially). The XPS depth profile suggested that near the passive film /HNSS interface, both Cr and Fe contents increased, but the Cr and Fe oxide/hydroxide contents decreased.
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页码:887 / 894
页数:7
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