Variable temperature EPR study of Fe2+ spin transition in Cu2+ doped [Fe(trz)(Htrz)2](BF4)

被引：0
|
作者：
C. Cantin
J. Kliava
Y. Servant
L. Sommier
O. Kahn
机构：
[1] Condensée de Bordeaux,Laboratoire des Sciences Moléculaires, Institut de Chimie de la Matière
[2] Université Bordeaux-I,Centre de Physique Moléculaire Optique et Hertzienne
来源：
Applied Magnetic Resonance | 1997年 / 12卷
关键词：
Electron Paramagnetic Resonance; Htrz; Hyperfine Structure; Spin Transition; Local Magnetic Field;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The temperature dependence of the EPR spectrum of Cu2+ in the range 293–393 K exhibits a low-spin (S=0) to high-spin (S=2) transition of the Fe2+ ions, with hysteresis (Tc↑=363 K,Tc↓=343 K). At 103 K, the principal values of theg and hyperfine tensors of Cu2+ ions are revealed by hyperfine structure.
引用
收藏
页码：87 / 93
页数：6
相关论文
共 50 条
  • [1] Variable temperature EPR study of Fe2+ spin transition in Cu2+ doped [Fe(trz)(Htrz)(2)](BF4)
    Cantin, C
    Kliava, J
    Servant, Y
    Sommier, L
    Kahn, O
    APPLIED MAGNETIC RESONANCE, 1997, 12 (01) : 87 - 93
  • [2] Variable Temperature EPR Study of Fe2+ Spin Transition in Cu2+ Doped [Fe(trz)(Htrz)2](BF4)
    Appl Magn Reson, 1 (87):
  • [3] Fe2+ spin transition in [Fe(trz)(Htrz)2](BF4) as evidenced by a variable temperature EPR study
    C. Cantin
    J. Kliava
    Y. Servant
    L. Sommier
    O. Kahn
    Applied Magnetic Resonance, 1997, 12 : 81 - 86
  • [4] Fe2+ Spin Transition in [Fe(trz)(Htrz)2](BF4) as Evidenced by a Variable Temperature EPR Study
    Cantin, C.
    Kliava, J.
    Servant, Y.
    Sommier, L.
    Applied Magnetic Resonance, 12 (01):
  • [5] Fe2+ spin transition in [Fe(trz)(Htrz)(2)](BF4) as evidenced by a variable temperature EPR study
    Cantin, C
    Kliava, J
    Servant, Y
    Sommier, L
    Kahn, O
    APPLIED MAGNETIC RESONANCE, 1997, 12 (01) : 81 - 86
  • [6] Synthesis and Characterization of [Fe(Htrz)2(trz)](BF4)] Nanocubes
    Blanco, Alexis A.
    Adams, Daniel J.
    Azoulay, Jason D.
    Spinu, Leonard
    Wiley, John B.
    MOLECULES, 2022, 27 (04):
  • [7] Piezoresistive Effect in the [Fe(Htrz)2(trz)](BF4) Spin Crossover Complex
    Diaconu, Andrei
    Lupu, Simona-Lacramioara
    Rusu, Ionela
    Risca, Ioan-Marian
    Salmon, Lionel
    Molnar, Gabor
    Bousseksou, Azzedine
    Demont, Philippe
    Rotaru, Aurelian
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (13): : 3147 - 3151
  • [8] In Situ AFM Imaging of Microstructural Changes Associated with The Spin Transition in [Fe(Htrz)2(Trz)](Bf4) Nanoparticles
    Manrique-Juarez, Maria D.
    Suleimanov, Iurii
    Hernandez, Edna M.
    Salmon, Lionel
    Molnar, Gabor
    Bousseksou, Azzedine
    MATERIALS, 2016, 9 (07)
  • [9] Dielectric and charge transport properties of the spin crossover complex [Fe(Htrz)2(trz)](BF4)
    Lefter, Constantin
    Gural'skiy, Il'ya A.
    Peng, Haonan
    Molnar, Gabor
    Salmon, Lionel
    Rotaru, Aurelian
    Bousseksou, Azzedine
    Demont, Philippe
    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2014, 8 (02): : 191 - 193
  • [10] Photoconduction in [Fe(Htrz)2(trz)](BF4)•H2O nanocrystals
    Etrillard, Celine
    Faramarzi, Vina
    Dayen, Jean-Francois
    Letard, Jean-Francois
    Doudin, Bernard
    CHEMICAL COMMUNICATIONS, 2011, 47 (34) : 9663 - 9665
12345