Zirconium-containing metal organic frameworks as solid acid catalysts for the N-formylation of aniline with formic acid

被引：1
|
作者：
Maria N. Timofeeva
Valentina N. Panchenko
Ivan A. Lukoyanov
Sung Hwa Jhung
机构：
[1] Boreskov Institute of Catalysis SB RAS,Department of Chemistry and Green
[2] Novosibirsk State Technical University,Nano Materials Research Center
[3] Kyungpook National University,undefined
来源：
Reaction Kinetics, Mechanisms and Catalysis | 2021年 / 133卷
关键词：
N-formylation; Aniline; Formic acid; Metal–organic framework; Brønsted acidity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Porous Zr-based metal–organic frameworks (MOF-808 and MOF-808/H2SO4, UiO-66 and UiO-66-SO3H) were used as solid acid catalysts for N-formylation of aniline with formic acid (aniline/formic acid 1/2 mol/mol, 35 °C). The yield of N-formylaniline was demonstrated to depend on structure of active sites and decrease in the order: MOF-808/H2SO4 > MOF-808 > UiO-66-SO3H > UiO-66. The activity of Zr-MOFs was dependent on the key properties of solvent, i.e. polarity and basicity. The MOF-808/H2SO4 was found to be the best catalyst, resulting in the formation of N-formylaniline in 96% yield under solvent free conditions. Efficiencies of MOF-808 and MOF-808/H2SO4 were higher in comparison with H-ZSM-5, zeolite natrolite and zeolite heulandite.
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页码：355 / 369
页数：14
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