The cyclopentadienyltitanium trichloride/MAO-catalysed polymerisation of methyl acrylate and copolymerisation with styrene and isoprene

被引：0
|
作者：
Ian D. Cunningham
Khatereh Fassihi
机构：
[1] University of Surrey,Chemistry
来源：
Polymer Bulletin | 2005年 / 53卷
关键词：
Polymer; Methyl; Molecular Weight; Alkene; Styrene;
D O I：
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摘要：
The polar electron-deficient alkene methyl acrylate was readily polymerised in good yield by the CpTiCl3-MAO system to give a polymer with a relatively low molecular weight, but reasonable polydispersity. The polymer appears to be atactic. The same system also gave a random sequence 1:1 copolymer of methyl acrylate and styrene, which according to NMR and SEM studies was a true copolymer rather than a blend.
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页码：359 / 365
页数：6
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