Theory of irreversible electrode reactions coupled to ion transfer across the liquid/liquid interface

被引：0
|
作者：
Milivoj Lovri
Šebojka Komorsky-Lovri
机构：
[1] “Rudjer Boškovi” Institute,Center for Marine and Environmental Research
来源：
Journal of Solid State Electrochemistry | 2006年 / 10卷
关键词：
Kinetics of electrode reaction; Liquid/liquid interface; Coupled electron and ion transfers;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Kinetically controlled electro-oxidation of a redox probe dissolved in the organic solvent, which is interposed between an electrode surface and an aqueous solution as a thin layer, is analyzed theoretically. It is demonstrated that the electrode reaction rate constant can be measured by the variation of scan rate in linear scan voltammetry both in the absence and in the superfluity of the supporting electrolyte dissolved in the film.
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页码：852 / 856
页数：4
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