Nonequilibrium Energy Transfer at Nanoscale: A Unified Theory from Weak to Strong Coupling

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作者
Chen Wang
Jie Ren
Jianshu Cao
机构
[1] Massachusetts Institute of Technology,Department of Chemistry
[2] Singapore-MIT Alliance for Research and Technology,Department of Physics
[3] Hangzhou Dianzi University,undefined
[4] Center for Phononics and Thermal Energy Science,undefined
[5] School of Physics Science and Engineering,undefined
[6] Tongji University,undefined
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摘要
Unraveling the microscopic mechanism of quantum energy transfer across two-level systems provides crucial insights to the optimal design and potential applications of low-dimensional nanodevices. Here, we study the non-equilibrium spin-boson model as a minimal prototype and develop a fluctuation-decoupled quantum master equation approach that is valid ranging from the weak to the strong system-bath coupling regime. The exact expression of energy flux is analytically established, which dissects the energy transfer as multiple boson processes with even and odd parity. Our analysis provides a unified interpretation of several observations, including coherence-enhanced heat flux and negative differential thermal conductance. The results will have broad implications for the fine control of energy transfer in nano-structural devices.
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