Metal-containing polymers based on disalicylidenediamines and their electrophysical properties

被引：0
|
作者：
A. G. Ivanov
B. V. Chernitsa
V. V. Shamanin
L. V. Vinogradova
机构：
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
[2] St. Petersburg State Technological Institute (Technical University),undefined
来源：
Russian Journal of Applied Chemistry | 2014年 / 87卷
关键词：
Lone Electron Pair; Electrophysical Property; Acceptor Interaction; Aromatic Diamine; Azomethine Group;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Metal-containing poly(disalicylidenediamines) exhibiting semiconductor properties were prepared by polycondensation of salicylidene derivatives of aromatic diamines with metal (Fe, Co, Ni, Cu) acetates. The data obtained confirm that the transfer of charge carriers in these polymers occurs along the chain through “nonclassical” polyconjugation zones formed via multiple intramolecular donor-acceptor interactions of lone electron pairs of the azomethine groups with the unoccupied d orbitals of the metal ions.
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页码：1693 / 1699
页数：6
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