An Efficient Synthesis of Chiral Alcohols via Catalytic Hydrogenation of Esters

被引：1
|
作者：
Yasunori Ino
Wataru Kuriyama
Osamu Ogata
Takaji Matsumoto
机构：
[1] Takasago International Corporation,Corporate Research & Development Division
来源：
Topics in Catalysis | 2010年 / 53卷
关键词：
Ester; Hydrogenation; Homogeneous; Ruthenium; Catalyst; Chiral; Alcohol; Amino alcohol; Diol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A ruthenium complex was found to catalyze the hydrogenation of chiral esters without the loss of their optical purities under mild and neutral conditions. This method can avoid a violent quench step and an extraction step which accompany conventional reduction using metal hydride reagents such as sodium borohydride and lithium aluminum hydride.
引用
收藏
页码：1019 / 1024
页数：5
相关论文
共 50 条
  • [1] An Efficient Synthesis of Chiral Alcohols via Catalytic Hydrogenation of Esters
    Ino, Yasunori
    Kuriyama, Wataru
    Ogata, Osamu
    Matsumoto, Takaji
    TOPICS IN CATALYSIS, 2010, 53 (15-18) : 1019 - 1024
  • [2] Efficient homogeneous catalytic hydrogenation of esters to alcohols
    Zhang, J
    Leitus, G
    Ben-David, Y
    Milstein, D
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (07) : 1113 - 1115
  • [3] Microscale Synthesis of Chiral Alcohols via Asymmetric Catalytic Transfer Hydrogenation
    Peeters, Christine M.
    Deliever, Rik
    De Vos, Dirk
    JOURNAL OF CHEMICAL EDUCATION, 2009, 86 (01) : 87 - 90
  • [4] CATALYTIC HYDROGENATION OF ESTERS TO ALCOHOLS
    ADKINS, H
    ORGANIC REACTIONS, 1954, 8 : 1 - 27
  • [5] The catalytic hydrogenation of esters to alcohols III
    Adkins, H
    Wojcik, B
    Covert, LW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1933, 55 : 1669 - 1676
  • [6] Efficient synthesis of chiral benzofuryl β-amino alcohols via a catalytic asymmetric Henry reaction
    Chen, Wei
    Zhou, Zhao-Hui
    Chen, Hong-Bin
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2017, 15 (06) : 1530 - 1536
  • [7] ENANTIOSELECTIVE SYNTHESIS OF HOMOALLYL ALCOHOLS VIA CHIRAL ALLYLBORONIC ESTERS
    HEROLD, T
    HOFFMANN, RW
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (10): : 768 - 769
  • [8] Catalytic Asymmetric Hydrogenation of α-Substituted Ketones and Aldehydes via Dynamic Kinetic Resolution: Efficient Approach to Chiral Alcohols
    Xie, Jian-Hua
    Zhou, Qi-Lin
    ALDRICHIMICA ACTA, 2015, 48 (02) : 33 - 40
  • [9] Efficient Synthesis of DOPA Analogues in Pepticinnamins E via Asymmetric Catalytic Hydrogenation of Dehydroamino Esters
    Sun, De-Qun
    Sun, Li
    Luo, Min
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (04) : 1731 - 1734
  • [10] Efficient Synthesis of Chiral β-Arylisopropylamines by Using Catalytic Asymmetric Hydrogenation
    Chen, Jian
    Zhang, Weicheng
    Geng, Huiling
    Li, Wei
    Hou, Guohua
    Lei, Aiwen
    Zhang, Xumu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (04) : 800 - 802
12345