Spectroscopy;
Phase Transition;
State Physics;
Thermal Expansion;
Expansion Coefficient;
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摘要:
An in situ x-ray diffraction study of Cs2ZnI4 crystals performed in the 4.2–300 K temperature range is reported. The lattice parameter measurements have revealed three anomalies corresponding to phase transitions. The thermal expansion coefficient along the c axis was found to vanish in the region of incommensurate and commensurate modulated phases, 120–96 K (the invar effect). A possible crystallographic model relating modulated atomic displacements to the invar effect is discussed.