Mixed-ligand lanthanide complexes with acylpyrazolones and phosphorus-containing ligands

被引：0

作者：

Yu. A. Belousov

A. A. Drozdov

P. P. Verteletskii

A. A. Prishchenko

L. I. Livantsova

O. P. Novikova

机构：

[1] Moscow State University,

来源：

Russian Journal of Coordination Chemistry | 2013年 / 39卷

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摘要：

The reactions of lanthanum acetylacetonate with various phosphorus-containing pesticides, toxic gases, and products of their hydrolysis are modeled by quantum-chemical methods. In the most cases, the enthalpy of substitution for water by organophosphorus compounds is negative. The complexes are studied in solutions using ethyl (diethoxyphosphoryl) acetate as a model compound. The mixed-ligand lanthanide complexes with acylpyrazolones and ethyl (diethoxyphosphoryl) acetate are synthesized. The crystal structure is determined for the samarium complex.

引用

页码：278 / 282

页数：4

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