Radiation-Induced Transformations of Iron(II) Formate

被引：0
|
作者：
V. N. Doroshenko
V. N. Kaurkovskaya
E. P. Yakubenko
D. I. Pobokin
I. R. Entinzon
V. M. Ogenko
机构：
[1] National Academy of Sciences of Ukraine,Institute of Surface Chemistry
来源：
High Energy Chemistry | 2002年 / 36卷
关键词：
Oxidation; Iron; Physical Chemistry; 2H2O; Crystallization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The solid-phase decomposition of the iron formate crystal hydrate Fe(HCOO)2 · 2H2O under exposure to 60Co γ-rays or 3.5-MeV electrons was studied. It was found that the irradiation of this salt to absorbed doses of 0.1–2 MGy resulted in the radiolysis of water of crystallization and the HCOO– anion and in the reduction or oxidation of the Fe2+ cation. The composition of the solid-phase (γ-Fe, α-Fe, FeO, γ-Fe ε-Fe2O3, Fe3O4, and FeCO3) and gaseous (H2O, CO, CO2, HCOOH, and CH4) radiolysis products of the substance was determined.
引用
收藏
页码：157 / 162
页数：5
相关论文
共 50 条
  • [1] Radiation-induced transformations of iron(II) formate
    Doroshenko, VN
    Kaurkovskaya, VN
    Yakubenko, EP
    Pobokin, DI
    Entinzon, IR
    Ogenko, VM
    HIGH ENERGY CHEMISTRY, 2002, 36 (03) : 157 - 162
  • [2] Features of Radiation-induced Transformations of Nickel Formate
    Doroshenko, V. N.
    Yakubenko, E. P.
    Denisenko, V. A.
    Kaurkovskaya, V. N.
    High Energy Chemistry, 30 (05):
  • [3] Features of radiation-induced transformations of nickel formate
    Doroshenko, VN
    Yakubenko, EP
    Denisenko, VA
    Kaurkovskaya, VN
    Entinzon, IR
    Ogenko, VM
    HIGH ENERGY CHEMISTRY, 1996, 30 (05) : 320 - 323
  • [4] RADIATION-INDUCED TRANSFORMATIONS OF POLYTRIFLUOROETHYLENE
    ILICHEVA, ZF
    BORZOV, SM
    SUKHOV, FF
    SLOVOKHOTOVA, NA
    KARPOV, VL
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1980, 22 (08): : 1723 - 1728
  • [5] KINETICS OF THE RADIATION-INDUCED REACTION OF IRON(III) WITH TIN(II)
    BOYLE, JW
    WEINER, S
    HOCHANADEL, CJ
    JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (06): : 892 - 896
  • [6] RADIATION-INDUCED TRANSFORMATIONS OF CELLULOSE ETHERS
    NUDGA, LA
    PETROPAVLOVSKII, GS
    PLISKO, EA
    ISAKOVA, OV
    ERSHOV, BG
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1987, 60 (08): : 1740 - 1744
  • [7] RADIATION-INDUCED REDUCTION OF VANADIUM(IV) TO VANADIUM(II) IN AQUEOUS PICOLINATE FORMATE SOLUTIONS
    ALHAYALY, LJH
    BUXTON, GV
    RADIATION PHYSICS AND CHEMISTRY, 1988, 32 (03) : 425 - 428
  • [8] PECULIARITIES OF RADIATION-INDUCED TRANSFORMATIONS IN CHROMIUM STEELS
    KHMELEVSKAYA, VS
    SOLOVYOV, SP
    GRABOVA, RB
    MALYNKIN, VG
    FIZIKA METALLOV I METALLOVEDENIE, 1990, (03): : 156 - 160
  • [9] TEMPORAL DEVELOPMENT OF RADIATION-INDUCED CELL TRANSFORMATIONS
    ROSSI, HH
    HALL, EJ
    MILLER, RC
    RADIATION RESEARCH, 1982, 91 (02) : 410 - 411
  • [10] RADIATION-INDUCED TRANSFORMATIONS OF CELLULOSE ETHERS.
    Nud'ga, L.A.
    Petropavlovskii, G.S.
    Plisko, E.A.
    Isakova, O.V.
    Ershov, B.G.
    Journal of applied chemistry of the USSR, 1987, 60 (8 Pt 2): : 1740 - 1744
12345