Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand

被引：0

作者：

J. G. Małecki

A. Maroń

机构：

[1] University of Silesia,Department of Crystallography, Institute of Chemistry

来源：

Transition Metal Chemistry | 2013年 / 38卷

关键词：

Ruthenium; PPh3; Natural Bond Orbital; Pyrrolidine; Natural Bond Orbital Analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Chloride and pseudohalide (N3−, NCS−) hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand were synthesized and characterized by IR, 1H, and 31P NMR, electronic absorption and emission spectroscopy and X-ray crystallography. The electronic structures of the complexes were calculated by density functional theory (DFT) on their crystal structures. The spin-allowed singlet–singlet electronic transitions of the complexes were calculated by time-dependent DFT, and the UV–Vis spectra have been discussed on these basis. The emission properties of the complexes were also studied.

引用

页码：133 / 142

页数：9

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