Sol-gel preparation of In2O3-Al2O3 supports with controlled textural and structural properties

被引:0
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作者
Vicente Rodríguez-González
Ricardo Gómez
Mario Moscosa-Santillan
Jacques Amouroux
机构
[1] Universidad Autónoma Metropolitana-I,Depto de Química
[2] Université Pierre et Marie Curie Paris 6,LGPPTS
关键词
Indium-doped alumina; sol-gel alumina; indium-alumina ; Al NMR-MAS; indium-alumina XRD; indium-alumina isopropanol dehydration;
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摘要
Alumina supports with a very narrow pore size distribution were obtained with indium-doped alumina prepared by the sol-gel method. The formation of aluminum in pentahedral coordination was identified by 27Al NMR-MAS-spectroscopy. A good correlation was obtained with the AlV NMR-MAS intensity signal and the activity in isopropanol dehydration. The insertion of In3+ substituting some Al3+ in the alumina network was suggested.
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页码:331 / 338
页数:7
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