Hydrophilicity and acid hydrolysis of water-soluble antibacterial iron(II) Schiff base complexes in binary aqueous solvents

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作者
Ali M. Shaker
Lobna A. E. Nassr
Mohamed S. S. Adam
Ibrahim M. A. Mohamed
机构
[1] Sohag University,Chemistry Department, Faculty of Science
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General Chemistry; Schiff Base; Acid Hydrolysis; Hydrolysis Rate; Schiff Base Ligand;
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摘要
Kinetics of acid hydrolysis of seven antibacterial iron(II) Schiff base complexes has been studied. The Schiff base ligands were derived from sodium 2-hydroxybenzaldehyde-5-sulfonate and a series of amino acids. The hydrolysis rate is studied by spectrophotometric method and compared with complex hydrophilicity. Addition of the organic co-solvent, dimethylsulfoxide or n-propanol, significantly accelerates the hydrolysis.
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页码:2460 / 2464
页数:4
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