Mechanism of the photolysis of substituted tetraphenylporphin with p-benzoquinones in vitro according to chemical nuclear polarization (CNP) data

被引:0
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作者
V. I. Porkhun
A. I. Rakhimov
机构
[1] Volgograd State Technical University,
来源
Russian Journal of Physical Chemistry A | 2012年 / 86卷
关键词
photolysis; benzoquinones; porphyrin; chemical nuclear polarization;
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学科分类号
摘要
It is established by means of chemical nuclear polarization that the photointeraction of quinones with porphyrin leads to the transfer of an electron with the formation of ion-radical pairs, and then to the transfer of a proton with the reversible reduction of quinone.
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页码:1915 / 1916
页数:1
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