Structural characteristics of peroxo complexes of group IV and V transition metals. Review

被引：0

作者：

V. S. Sergienko

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

来源：

Crystallography Reports | 2004年 / 49卷

关键词：

Vanadium; Structural Characteristic; Versus Transition; Peroxo Complex; Trans Effect;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Structural characteristics of peroxo complexes of transition metals of Groups IV and V (Ti, V, Nb, and Ta) with the ratios M: O2 = 1: 1, 1: 2, 1: 3, and 1: 4 and alkyl peroxo complexes of Ti, Hf, and V have been considered. The structural manifestation of the trans effect of η2-coordinated peroxo ligand in pseudooctahedral Ti, Nb, and V monoperoxo complexes is characterized. The structural manifestations of the trans effect of multiply bonded peroxo and oxo ligands in monooxomonoperoxo complexes of vanadium(V) are compared.

引用

页码：907 / 929

页数：22

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