Synthesis of tetrasubstituted furans by multicomponent reaction of alkynes with dichloro(ethyl)aluminum and carboxylic acid esters in the presence of Cp2TiCl2

被引:0
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作者
L. O. Khafizova
M. G. Shaibakova
N. M. Chobanov
R. R. Gubaidullin
T. V. Tyumkina
U. M. Dzhemilev
机构
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
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关键词
Furan; Ethyl Acrylate; Furan Derivative; Carboxylic Acid Ester; Comprehensive Heterocyclic Chemistry;
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摘要
A one-pot procedure has been developed for the synthesis of 3,4-dialkyl-2,5-dicycloalkyl(aryl, hetaryl)furans in 38–82% yield by reaction of symmetrical alkynes with cycloalkane(arene, hetarene)carboxylic acid esters and EtAlCl2 in the presence of Cp2TiCl2 as catalyst.
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页码:1277 / 1281
页数:4
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