Flame retardancy and its mechanism of polymers flame retarded by DBDPE/Sb2O3

被引:0
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作者
Jian-dong Zuo
Rong-xun Li
Shao-hua Feng
Guang-ye Liu
Jian-qing Zhao
机构
[1] South China University of Technology,College of Materials Science and Engineering
[2] Qingdao University of Science and Technology,Key Laboratory of New Materials of Qingdao
关键词
decabromodiphenylethan (DBDPE); thermogravimetry; gas phase flame retarding;
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学科分类号
摘要
The flammability characterization and thermal composition of polymers flame retarded by decabromodiphenylethane (DBDPE) and antimony trioxide (Sb2O3) were studied by cone calorimeter and thermogravimetry (TG). The results show that ABS/DBDPE/Sb2O3 has the similar flammability parameters and thermal composition curves to ABS/DBDPO/Sb2O3. It suggests that DBDPE/Sb2O3 has the similar flame retardant behavior to DBDPO/Sb2O3. The heat release rate (HRR) and the effect heat combustion (EHC) curves of polymers flame retarded by DBDPE/Sb2O3 all decrease, but the mass loss rate (MLR) curve slightly increase. It shows that the decrease of HRR is not due to the increase of char formation ratio but the generation of incombustible gases. The major flame retardant mechanism of DBDPE/Sb2O3 is gas phase flame retardant mechanism. Increasing content of Sb2O3 in DBDPE/Sb2O3 can improve the flame retardant property and thermal stability of acrylonitrile butadiene styrene. Sb2O3 has a good synergistic effect with DBDPE.
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页码:64 / 68
页数:4
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