Structure of the template complex formed in the Co(III)-dithiooxamide-acetone ternary system during complex formation in the KCoFe(CN)6-gelatin immobilized matrices

被引：0

作者：

D. V. Chachkov

O. V. Mikhailov

机构：

[1] Kazan State Technological University,

来源：

Russian Journal of Inorganic Chemistry | 2010年 / 55卷

关键词：

Hexacyanoferrate; Dithio; Hydroxide Anion; Template Process; Template Complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The geometry of a macrocyclic Co(III) complex is calculated by the B3LYP hybrid density functional method with the 6-31G(d) basis set. The Co(III) complex is formed with 4,6,6-trimethyl-2,8-dithio-3,7-diazanonene-4-dithioamide-1,9, a water molecule, and a hydroxide anion due to the template process between gelatin-immobilized cobalt(III) hexacyanoferrate(II), dithiooxamide, and acetone. The bond lengths and the bond and dihedral angles in the complex with the MN2S2 metallochelate core are presented. Contrary to expectations, this metallochelate core is not planar, whereas the additional six-membered metallocycle formed due to template “cross-linking” is at an angle of ∼57° to two five-membered rings and is also nonplanar.

引用

页码：1243 / 1247

页数：4

共 12 条

[1] Structure of the template complex formed in the Co(III)-dithiooxamide-acetone ternary system during complex formation in the KCoFe(CN)6-gelatin immobilized matrices
Chachkov, D. V.
Mikhailov, O. V.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (08) : 1243 - 1247
[2] Mild template synthesis in the ternary system Co(II)-dithiooxamide-acetone in gelatin-immobilized Co2[Fe(CN)6] matrix implantates
Mikhailov, O. V.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (01) : 82 - 89
[3] Mild template synthesis in the ternary system Co(II)-dithiooxamide-acetone in gelatin-immobilized Co2[Fe(CN)6] matrix implantates
O. V. Mikhailov
Russian Journal of General Chemistry, 2008, 78 : 82 - 89
[4] Soft template synthesis of Co(III)-dithiooxamide-glyoxal in KCoFe(CN)6-gelatin-immobilized matrix systems
Mikhailov, OV
Khamitova, AI
ZHURNAL OBSHCHEI KHIMII, 1997, 67 (12): : 2028 - 2035
[5] Mild template synthesis in the Ni(II)-dithiooxamide-acetone ternary system in Ni2[Fe(CN)6] gelatin-immobilized matrix implantates
Mikhajlov, O.V.
Koordinatsionnaya Khimiya, 2002, 28 (01): : 34 - 41
[6] Mild template synthesis in the Ni(II)-dithiooxamide-acetone ternary system in Ni2[Fe(CN)6] gelatin-immobilized matrix implantates
Mikhailov, OV
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2002, 28 (01) : 32 - 37
[7] Complexation in a binary Co(III)-N,N′-diphenylthiooxamide system in the gelatin-immobilized KCoFe(CN)6 matrices
Mikhailov, OV
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2000, 26 (04) : 266 - 271
[8] Mild Template Synthesis in the Ni(II)–Dithiooxamide–Acetone Ternary System in Ni2[Fe(CN)6] Gelatin-Immobilized Matrix Implantates
O. V. Mikhailov
Russian Journal of Coordination Chemistry, 2002, 28 : 32 - 38
[9] Low-temperaturic template synthesis of macrocyclic cobalt(III) chelates with (N,N,S,S)-donor atomic ligands in the cobalt(II)-dithiooxamide-formaldehyde and cobalt(II)-dithiooxamide-glyoxal systems in the Co2[Fe(CN)6]-gelatin-immobilized matrices
Mikhailov, OV
Khamitova, AI
TRANSITION METAL CHEMISTRY, 2000, 25 (01) : 26 - 31
[10] Low-temperaturic template synthesis of macrocyclic cobalt(III) chelates with (N,N,S,S)-donor atomic ligands in the cobalt(II)–dithiooxamide-formaldehyde and cobalt(II)–dithiooxamide-glyoxal systems in the Co2[Fe(CN)6]-gelatin-immobilized matrices
Oleg V. Mikhailov
Albina I. Khamitova
Transition Metal Chemistry, 2000, 25 : 26 - 31

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