Chemoselective noncatalytic addition of secondary phosphine chalcogenides to citral

被引：0
|
作者：
N. K. Gusarova
N. I. Ivanova
N. A. Konovalova
A. I. Albanov
L. M. Sinegovskaya
N. D. Avseenko
B. G. Sukhov
A. I. Mikhaleva
A. V. Gusarov
B. A. Trofimov
机构：
[1] Russian Academy of Sciences,Favorsky Irkutsk Institute of Chemistry, Siberian Branch
来源：
Russian Journal of General Chemistry | 2007年 / 77卷
关键词：
Phosphine; Phosphine Oxide; Octadienal; Secondary Phosphine; Phosphine Selenide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Addition of secondary phosphine oxides, phosphine sulfides and phosphine selenides to 3,7-dimethyl-2,6-octadienal (citral) (48–50°C, THF, argon) proceeds exclusively to the aldehyde group giving rise to new polyfunctional tertiary phosphine chalcogenides with diene and hydroxyl moieties in high preparative yield (up to 80%).
引用
收藏
页码：409 / 414
页数：5
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