Low Temperature Specific Heat and Thermal Stability of Fe–B Ultrafine Amorphous Alloy Particles

被引:0
|
作者
L. Wang
Z. C. Tan
S. H. Meng
D. B. Liang
S. J. Ji
Z. K. Hei
机构
[1] Chinese Academy of Sciences,Thermochemistry Laboratory, Dalian Institute of Chemical Physics
[2] Chinese Academy of Sciences,Environmental Engineering Laboratory, Dalian Institute of Chemical Physics
[3] Dalian Maritime University,Institute of Material and Technology
关键词
DSC; Fe–B amorphous alloy; specific heat; thermal stability; ultrafine particle;
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中图分类号
学科分类号
摘要
Fe–B ultrafine amorphous alloy particles (UFAAP) were prepared by chemical reduction of Fe3+ with NaBHO4 and confirmed to be ultrafine amorphous particles by transmission electron microscopy and X-ray diffraction. The specific heat of the sample was measured by a high precision adiabatic calorimeter, and a differential scanning calorimeter was used for thermal stability analysis. A topological structure of Fe-B atoms is proposed to explain two crystallization peaks and a melting peak observed at T=600, 868 and 1645 K, respectively.
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页码:409 / 414
页数:5
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