Geochemical fractionation, bioavailability, ecological and human health risk assessment of metals in topsoils of an emerging industrial cluster near New Delhi

Urban spaces have become sink for metal-rich waste, particularly in unorganized industrial clusters and metro-cities. Geochemical distribution of metals in different forms and their mobility and bioavailability in topsoils of Bhiwadi Industrial Cluster (BIC) near New Delhi are studies following m-BCR-SEP. Contamination factor (Cf), risk assessment code (RAC), ecological risk assessment (Er), and carcinogenic and non-carcinogenic health risk (HRA) were calculated to assess health and environmental risks. Residual fraction (F4) contained considerable amounts of Cd (57.2%), Cr (81.5%), Fe (86.1%), Mn (62.5%), Ni (58.3%), and V (71.4%). Pb was present in reducible fraction (F2; 52.8%), whereas Cu was distributed in F2 (33.3%) and F4 (31.6%). Zn showed equal distribution in acid exchangeable (F1; 33.9%) and oxidizable fraction (F3; 32.5%). High Cf was observed for Zn (0.9–20.9), Cu (0.46–17) and Pb (0.2–9.9). RAC indicated high risk of Cd, Cu, Mn, Ni, and Zn due to their high mobility and toxicity. High potential bioavailability of Cu, Pb, and Zn (> 65%) was found in samples collected near to metal casting, electroplating, and automobile part manufacturing industries. Considerable to extremely high ecological risk was observed for Cd, low to high risk for Cu, low risk to moderate risk for Cr, Mn, Ni, Zn, and Pb. All topsoil samples were in low to very high-risk range for metals. Ingestion was major pathway of metals followed by dermal and inhalation. Children were more prone to non-carcinogenic risks (hazardous index: 3.6). Topsoils had high carcinogenic risk to exposed population for Cd, Cr, Ni, and Pb.