Photobiocatalysts tame nitrogen-centred radicals

被引：0
|
作者：
Marc Garcia-Borràs
机构：
[1] Universitat de Girona,Institut de Quı́mica Computacional i Catàlisi and Departament de Quı́mica
来源：
Nature Catalysis | 2023年 / 6卷
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摘要：
Enzymes are capable of controlling the reactivity and selectivity of catalytic mechanisms involving highly reactive intermediates. Now, flavine mononucleotide-dependent ene-reductases have been repurposed as photobiocatalysts for generating and taming unstable N-centred radicals, enabling their application in asymmetric radical C–N couplings.
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页码：654 / 656
页数：2
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