Heterocyclic derivatives of fullerene C60. 1. Synthesis of new fulleropyrazolines by the 1,3-dipolar cycloaddition of nitrile imines

被引：0

作者：

Reinov M.V. ^{[1
]}

Yurovskaya M.A. ^{[1
]}

Davydov D.V. ^{[1
]}

Streletskii A.V. ^{[1
]}

机构：

[1] Moscow M. V. Lomonosov State Univ.

来源：

Chemistry of Heterocyclic Compounds | 2004年 / 40卷 / 2期

关键词：

1,3-dipolar cycloaddition; 2,5-diaryltetrazoles; 6,6]-closed cycloadducts; Fullerene C[!sub]60[!/sub; Fulleropyrazolines; Hydrazonoyl halides; Nitrile imines;

D O I：

10.1023/B:COHC.0000027890.05668.07

中图分类号：

学科分类号：

摘要：

New stable [6,6]-closed cycloadducts, fulleropyrazolines containing aryl, hetaryl, trifluoromethyl, and other substituents in the five-membered ring, have been obtained by the 1,3-dipolar cycloaddition of nitrile imines to C 60. Two methods of generating nitrile imines in situ have been used, the dehydrohalogenation of the corresponding hydrazonoyl halides by the action of triethylamine and the thermal decomposition of 2,5-diaryltetrazoles.

引用

页码：188 / 193

页数：5

共 50 条

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