Electronic excitations of Sc3+ impurity in α-Al2O3 crystals

被引:0
|
作者
B. R. Namozov
R. I. Zakharchenya
M. P. Korobkov
V. V. Mürk
机构
[1] Russian Academy of Sciences,A. F. Ioffe Physicotechnical Institute
[2] Institute of Physics,undefined
来源
关键词
Spectroscopy; State Physics; Absorption Band; Optical Property; Corundum;
D O I
暂无
中图分类号
学科分类号
摘要
Optical properties, including luminescence, of scandium-doped α-Al2O3 crystals have been studied in the VUV range. An absorption band associated with the scandium impurity was observed at the fundamental-absorption edge of crystalline corundum. A strong luminescence band peaking at 5.6 eV, which is most effectively excited within the 7.7–8.8-eV interval, was found. The kinetic and polarization characteristics of this luminescence were studied within the temperature range 6–500 K. An excitation model of the impurity complex and the mechanism of its relaxation are discussed.
引用
收藏
页码:599 / 600
页数:1
相关论文
共 50 条
  • [1] Electronic excitations of Sc3+ impurity in α-Al2O3 crystals
    Namozov, BR
    Zakharchenya, RI
    Korobkov, MP
    Murk, VV
    [J]. PHYSICS OF THE SOLID STATE, 1998, 40 (04) : 599 - 600
  • [2] Self-trapping and multiplication of electronic excitations in Al2O3 and Al2O3:Sc crystals
    Kirm, M
    Zimmerer, G
    Feldbach, E
    Lushchik, A
    Lushchik, C
    Savikhin, F
    [J]. PHYSICAL REVIEW B, 1999, 60 (01): : 502 - 510
  • [3] Electronic excitations and defects in nanostructural Al2O3
    S. V. Gorbunov
    A. F. Zatsepin
    V. A. Pustovarov
    S. O. Cholakh
    V. Yu. Yakovlev
    [J]. Physics of the Solid State, 2005, 47 : 733 - 737
  • [4] Electronic excitations and defects in nanostructural Al2O3
    Gorbunov, SV
    Zatsepin, AF
    Pustovarov, VA
    Cholakh, SO
    Yakovlev, VY
    [J]. PHYSICS OF THE SOLID STATE, 2005, 47 (04) : 733 - 737
  • [5] IMPURITY STRIATION IN AL2O3 SINGLE-CRYSTALS
    BELAYA, AN
    DOBROVINSKAYA, ER
    LITVINOV, LA
    PISHCHIK, VV
    FISUN, AI
    CHERNYAKOV, EI
    [J]. KRISTALLOGRAFIYA, 1977, 22 (02): : 411 - &
  • [6] Kinetics of the electronic center annealing in Al2O3 crystals
    Kuzovkov, V. N.
    Kotomin, E. A.
    Popov, A. I.
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2018, 502 : 295 - 300
  • [7] Study on the Solid and Solution Properties of Sc3+ and Al3+ in (Tb, Sc)3 (Sc, Al)5O12 Crystals Grown by the Czochralski Method
    Li, Laichao
    Chen, Tengbo
    Yu, Yuxi
    Zhang, Sa
    Yu, Zhiyang
    [J]. CRYSTAL GROWTH & DESIGN, 2023, 23 (08) : 5950 - 5956
  • [8] Electronic and optical properties of Θ-Al2O3 and comparison to α-Al2O3
    Mo, SD
    Ching, WY
    [J]. PHYSICAL REVIEW B, 1998, 57 (24) : 15219 - 15228
  • [9] Spectral-kinetic study of self-trapping and multiplication of electronic excitations in Al2O3 crystals
    Lushchik, A.
    Feldbach, E.
    Kirm, M.
    Liblik, P.
    Lushchik, Ch.
    Martinson, I.
    Savikhin, F.
    Zimmerer, G.
    [J]. Journal of Electron Spectroscopy and Related Phenomena, 101 : 587 - 591
  • [10] Spectral-kinetic study of self-trapping and multiplication of electronic excitations in Al2O3 crystals
    Lushchik, A
    Feldbach, E
    Kirm, M
    Liblik, P
    Lushchik, C
    Martinson, I
    Savikhin, F
    Zimmerer, G
    [J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1999, 101 : 587 - 591