Reactions of Tin and Lead with Tricarbonylcyclopentadienylmolybdenum(II) and Tricarbonylcyclopentadienyltungsten(II) Chlorides

被引：0
|
作者：
A. V. Piskunov
S. V. Maslennikov
I. V. Spirina
V. P. Maslennikov
A. N. Artemov
机构：
[1] Lobachevskii Nizhny Novgorod State University,Research Institute of Chemistry
来源：
Russian Journal of General Chemistry | 2002年 / 72卷
关键词：
Oxidation; Chloride; Metal Surface; Thermodynamic Parameter; Organometallic Compound;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Tin was oxidized with tricarbonylcyclopentadienylmolybdenum and tricarbonylcyclopentadienyltungsten chlorides to obtain polynuclear organometallic compounds [η5-C5H5M(CO)3]2SnCl2 (M = Mo, W). The reactions of the above-mentioned oxidants with lead gave lead chloride and [η5-C5H5M(CO)3]2 dimers. Formal-kinetic regularities of tin oxidation with tricarbonylcyclopentadienylmolybdenum chloride in N,N-dimethylformamide were found. Thermodynamic parameters of adsorption of the reagent on the metal surface were determined.
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页码：65 / 67
页数：2
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