N-Substituted α-trifluoromethyl β-nitro amines in the synthesis of fluorine-containing 1,2-diamines, amino alcohols, and β-amino acids

被引:0
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作者
V. Yu. Korotaev
A. Yu. Barkov
M. I. Kodess
I. B. Kutyashev
P. A. Slepukhin
A. Ya. Zapevalov
机构
[1] A. M. Gorky Ural State University,I. Ya. Postovsky Institute of Organic Synthesis
[2] Ural Branch of the Russian Academy of Sciences,undefined
来源
Russian Chemical Bulletin | 2009年 / 58卷
关键词
diazo compounds; nitroalkenes; organofluorine compounds; amines; amino alcohols; β-amino acids; X-ray diffraction analysis;
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摘要
Reactions of 2-diazo-1,1,1-trifluoro-3-nitropropane or 1-trifluoromethyl-2-nitroethenes with amines and amino alcohols afforded N-mono- and N,N-disubstituted α-trifluoromethyl β-nitro amines, which were used to obtain a number of trifluoromethyl-containing 1,2-diamines, amino alcohols, and β-amino acids.
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页码:1886 / 1898
页数:12
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