Supported ruthenium catalysts in hydrodechlorination of CCl2F2 (CFC-12)

被引：0
|
作者：
A. Malinowski
W. Juszczyk
M. Bonarowska
M. Wojciechowska
Z. Kowalczyk
Z. Karpiñski
机构：
[1] Polish Academy of Sciences,Institute of Physical Chemistry
[2] A. Mickiewicz University,Faculty of Chemistry
[3] Warsaw Technical University,Faculty of Chemistry
来源：
Reaction Kinetics and Catalysis Letters | 1999年 / 68卷
关键词：
CCl; F; hydrodechlorination; supported Ru catalysts; selectivity to CHClF; selectivity to C; -products;
D O I：
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中图分类号：
学科分类号：
摘要：
Active carbon-and MgF2-supported ruthenium catalysts characterized by a comparable metal dispersion were investigated in CCl2F2 hydrodechlorination. Ruthenium, especially when supported on carbon, exhibits a considerable selectivity to CHClF2. This propensity and a noticeable activity towards C2-products differentiate ruthenium from palladium catalysts.
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页码：53 / 60
页数：7
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