Synthesis of 2-amino derivatives of levoglucosenone

被引:0
|
作者
F. A. Valeev
L. Kh. Kalimullina
Sh. M. Salikhov
O. V. Shitikova
I. P. Tsypysheva
M. G. Safarov
机构
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Scientific Center
[2] Bashkir State University,undefined
来源
关键词
levoglucosenone; amino sugar; mucopolysaccharides; ketose oximes and hydrazone; nucleophilic substitution; aminolysis; 1,6-anhydro sugar sulfonates;
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摘要
2-Amino derivatives of levoglucosenone were prepared by reaction of the 2-methanesulfonyl (or p-toluenesulfonyl) derivatives with ammonia, methylamine, or octylamine under various conditions. The analogous reaction did not occur for saturated derivative 15. The 2-amino-3,4-dihydro derivative was prepared by catalytic hydrogenation of unsaturated amine 9.
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页码:521 / 525
页数:4
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