Thermal stability of new complexes bearing both acrylate and aliphatic amine as ligands

被引：0
|
作者：
Mihaela Badea
Rodica Olar
Dana Marinescu
Gina Vasile
机构：
[1] University of Bucharest,Faculty of Chemistry, Department of Inorganic Chemistry
[2] University of Agronomical Sciences and Veterinary Medicine,Department of Agrochemistry
来源：
Journal of Thermal Analysis and Calorimetry | 2008年 / 92卷
关键词：
acrylate; carbonate; complexes; ethylenediamine; thermal stability;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
This paper reports the investigation of the thermal stability of a series of new complexes with mixed ligands of the type [M(en)(C3H3O2)2]·nH2O ((1) M=Ni, n=2; (2) M=Cu, n=0; (3) M=Zn, n=2; en=ethylenediamine and (C3H3O2)=acrylate anion). The thermal behaviour steps were investigated in a nitrogen flow. The thermal transformations are complex processes according to TG and DTA curves including dehydration, ethylenediamine elimination as well as acrylate thermolysis. The final products of decomposition are the most stable metal oxides except for complex (2) that generates metallic copper.
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页码：205 / 208
页数：3
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