Solubility of d-elements salts in organic and aqueous-organic solvents: III. Influence of intermolecular association on solubility of cadmium bromide and iodide

被引：0
|
作者：
N. A. Bogachev
A. O. Gorbunov
A. B. Nikolskii
M. Yu. Skripkin
机构：
[1] St. Petersburg State University,
来源：
Russian Journal of General Chemistry | 2016年 / 86卷
关键词：
structure of liquid; complex formation; cadmium halides; competing solvation;
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学科分类号：
摘要：
Solubility in the systems CdX2–H2O–Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25°C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.
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页码：1539 / 1544
页数：5
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