Metal-organic framework and inorganic glass composites

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作者
Louis Longley
Courtney Calahoo
René Limbach
Yang Xia
Joshua M. Tuffnell
Adam F. Sapnik
Michael F. Thorne
Dean S. Keeble
David A. Keen
Lothar Wondraczek
Thomas D. Bennett
机构
[1] University of Cambridge,Department of Materials Science and Metallurgy
[2] Otto Schott Institute of Materials Research,undefined
[3] University of Jena,undefined
[4] Diamond Light Source Ltd.,undefined
[5] Diamond House,undefined
[6] Harwell Campus,undefined
[7] ISIS Facility,undefined
[8] Rutherford Appleton Laboratory,undefined
[9] Harwell Campus,undefined
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摘要
Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.
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