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A Luminescent Metal-Organic Framework with LON Topology for Highly Effective Fluorescence Sensing of Fe3+ and TNP
被引:0
|作者:
Yu Gu
Rui Lin
Xiaolong Luo
Yunling Liu
机构:
[1] Changchun University of Technology,Advanced Institute of Materials Science, School of Chemistry and Life Science
[2] Jilin University,State Key Laboratory of Inorganic Synthesis & Preparative Chemistry
来源:
关键词:
Metal-organic framework;
Fluorescence quenching;
Fe;
2,4,6-Trinitrophenol(TNP);
D O I:
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学科分类号:
摘要:
A luminescent Ag-based metal-organic framework(compound 1) has been synthesized and its structure has been characterized. Compound 1 was fabricated using the Ag+ and bbimb2− ligands and manifestes a rare LON topology. Compound 1 is selective not only in detecting traces of Fe3+ and 2,4,6-trinitrophenol(TNP) via luminescence quenching, but also demonstrates high selectivity in the presence of other competitors. Compound 1’s Ksv values towards Fe3+ can reach as high as 9.3×l03 L/mol, which is higher than those of several other MOF materials. It is also a recyclable luminous sensor with the potential to be utilized for detecting TNP. Hence, based on its characteristics, compound 1 can be regarded as a prospective luminescence sensor for detecting Fe3+ and TNP.
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页码:305 / 309
页数:4
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