Nano-sized manganese-calcium cluster in photosystem II

被引：0
|
作者：
M. M. Najafpour
M. Z. Ghobadi
B. Haghighi
J. J. Eaton-Rye
T. Tomo
J. -R. Shen
S. I. Allakhverdiev
机构：
[1] Institute for Advanced Studies in Basic Sciences (IASBS),Department of Chemistry
[2] Institute for Advanced Studies in Basic Sciences (IASBS),Center of Climate Change and Global Warming
[3] University of Otago,Department of Biochemistry
[4] Tokyo University of Science,Department of Biology, Faculty of Science
[5] Japan Science and Technology Agency (JST),PRESTO
[6] Okayama University,Graduate School of Natural Science and Technology, Faculty of Science, Photosynthesis Research Center
[7] Russian Academy of Sciences,Controlled Photobiosynthesis Laboratory, Institute of Plant Physiology
[8] Russian Academy of Sciences,Institute of Basic Biological Problems
来源：
Biochemistry (Moscow) | 2014年 / 79卷
关键词：
manganese; calcium; nano-sized manganese-calcium cluster; oxygen; photosynthesis; water oxidation; wateroxidizing complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Cyanobacteria, algae, and plants are the manufacturers that release O2 via water oxidation during photosynthesis. Since fossil resources are running out, researchers are now actively trying to use the natural catalytic center of water oxidation found in the photosystem II (PS II) reaction center of oxygenic photosynthetic organisms to synthesize a biomimetic supercatalyst for water oxidation. Success in this area of research will transcend the current bottleneck for the development of energy-conversion schemes based on sunlight. In this review, we go over the structure and function of the water-oxidizing complex (WOC) found in Nature by focusing on the recent advances made by the international research community dedicated to achieve the goal of artificial water splitting based on the WOC of PS II.
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页码：324 / 336
页数：12
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