Study of the supramolecular interactions of carboxylic acids used as versatile ligands in coordination chemistry

被引：0
|
作者：
C. C. Corrêa
F. M. Scaldini
F. C. Machado
C. B. Pinheiro
机构：
[1] Universidade Federal de Minas Gerais,Departamento de Física
[2] Belo Horizonte-MG,ICEX
[3] Universidade Federal de Juiz de Fora,Departamento de Química
[4] Juiz de Fora-MG,ICE
来源：
Journal of Structural Chemistry | 2016年 / 57卷
关键词：
supramolecular arrangement; carboxylate ligands; X-ray diffraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Carboxylate ligands are very versatile because they can adopt different coordination modes towards metal cations, such as monodentate, bidentate-chelate, bidentate bridging and monoatomic bridging. Because of this versatility, these ligands have been widely used in coordination chemistry. In this study the three dimensional structure of the crystal arrangement of 2,5-thiophenedicarboxylic (H2TPD), trans-3-(3- pyridyl)acrylic (HPYA), and 4,4′-sulfonyldibenzoic (H2SFD) acids are determined in order to investigate their supramolecular properties for coordination polymers and metal-organic framework (MOF) constructions.
引用
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页码：1235 / 1242
页数：7
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