Ferromagnetism in Cu-doped ZnO nanoparticles at room temperature

被引:0
|
作者
H. L. Liu
J. H. Yang
Y. J. Zhang
Y. X. Wang
M. B. Wei
D. D. Wang
L. Y. Zhao
J. H. Lang
M. Gao
机构
[1] Changchun Institute of Optics,Key Laboratory of Excited State Processes
[2] Fine Mechanics and Physics,undefined
[3] Chinese Academy of Sciences,undefined
[4] Graduate School of the Chinese Academy of Sciences,undefined
[5] Physics College of Jilin Normal University,undefined
关键词
Magnetic Semiconductor; Room Temperature Ferromagnetism; Citric Acid Complex; Exhibit Room Temperature; Short Separation Distance;
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中图分类号
学科分类号
摘要
Cu-doped ZnO nanoparticles were successfully synthesized and structurally characterized by using X-ray diffraction (XRD) and transmission electron microscope (TEM). XRD shows that Zn1−xCuxO (x ≤ 0.04) samples are single phase with the ZnO-like wurtzite structure, while the secondary phase Cu is observed in Zn0.95Cu0.05O sample. Magnetic measurements indicated that Zn1−xCuxO (x = 0.02, 0.03, 0.04) are ferromagnetic at room temperature and the magnetic moment per Cu atom decreased with increasing Cu concentration. XRD, TEM and X-ray photoelectron spectroscopy (XPS) analysis revealed that no ferromagnetic-related secondary phase was detected. The origin of the ferromagnetism in Zn1−xCuxO (x ≤ 0.04) was mainly due to Cu ions substituted into the ZnO lattice.
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页码:628 / 631
页数:3
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